Effect of the medium on the oxidation of aliphatic monocarboxylic acids |
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| Authors: | V E Agabekov G V Butovskaya V A Azarko and N I Mitskevich |
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| Institution: | (1) Institute of Physical Organic Chemistry, Minsk, USSR |
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| Abstract: | Oxidation rates and k2/ k6 ratios are given for some acids from propionic to lauric. The k2/k6 ratio is shown to be influenced by the electrostatic effect of the solvent. A linear dependence between the isodielectric values of k2/k6 and the number of methylene groups in the acid molecules is described.
                 k2/k6     .    k2/k6    k2/k6  .
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