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Polyfluoroalkyl <Emphasis Type="Italic">N</Emphasis>-(trifluoromethylsulfonyl)amidosulfites,number one stable NH-containing amidosulfites
Authors:B A Shainyan  L L Tolstikova
Institution:(1) Faworsky Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, 664033, Russia
Abstract:We prepared for the first time NH-containing amidosulfites, polyfluoroalkyl N-(trifluoro-methylsulfonyl) amidosulfites CF3SO2NHS(O)ORF, by reaction of N-sulfinyl-trifluoromethanesulfonamide CF3SO2N=S=O with alcohols RFOH. Amidosulfites were formed also in reaction of chlorosulfites RFOS(O)Cl with trifluoromethanesulfonamide, with its sodium salt, and N-trimethylsilyl derivative.
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