配合物[Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]的合成及晶体结构 |
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作者姓名: | 咸春颖 林苗 |
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作者单位: | 东华大学化学与化工学院,上海,200051 |
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基金项目: | 上海市青年基金资助项目(No.2000QN34)。 |
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摘 要: | The new complex [Ce(CH2=C(CH3)COO)2(NO3)(Phen)]2 was prepared in ethanol-aqueous solution with 8-hydroxyquinoline as the acidity regulator. Its crystal structure was determined by X-ray diffraction analysis. The title complex is triclinic, space group P1, a=1.00832(3)nm, b=1.02858(8)nm, c=1.12350(8)nm, α=113.9250(10)°, β=103.8210(10)°, γ=81.4650(10)°, V=1.03252(14)nm3, Z=1, Dc=1.700g·cm-3, F(000)=522. The coordination number of Ce3+ is nine. CCDC: 211278.
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关 键 词: | 配合物 合成 晶体结构 |
修稿时间: | 2003-04-08 |
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