| 配合物[Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]的合成及晶体结构 |
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| 引用本文： | 咸春颖,林 苗.配合物[Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]的合成及晶体结构[J].无机化学学报,2003,19(9):1030-1032. |
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| 作者姓名： | 咸春颖 林 苗 |
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| 作者单位： | 东华大学化学与化工学院,上海,200051 |
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| 基金项目： | 上海市青年基金资助项目(No.2000QN34)。 |
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| 摘 要： | The new complex Ce(CH2=C(CH3)COO)2(NO3)(Phen)]2 was prepared in ethanol-aqueous solution with 8-hydroxyquinoline as the acidity regulator. Its crystal structure was determined by X-ray diffraction analysis. The title complex is triclinic, space group P1, a=1.00832(3)nm, b=1.02858(8)nm, c=1.12350(8)nm, α=113.9250(10)°, β=103.8210(10)°, γ=81.4650(10)°, V=1.03252(14)nm3, Z=1, Dc=1.700g·cm-3, F(000)=522. The coordination number of Ce3+ is nine. CCDC: 211278.
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| 关 键 词： | 配合物 合成 晶体结构 |
| 修稿时间： | 2003年4月8日 |
Synthesis and Crystal Structure of the Complex [Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]2 |
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| XIAN Chun-Ying and LIN Miao.Synthesis and Crystal Structure of the Complex [Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]2[J].Chinese Journal of Inorganic Chemistry,2003,19(9):1030-1032. |
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| Authors: | XIAN Chun-Ying and LIN Miao |
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| Institution: | College of Chemistry and Chemical Engineering, Donghua University, Shanghai 200051 and College of Chemistry and Chemical Engineering, Donghua University, Shanghai 200051 |
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| Abstract: | |
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| Keywords: | complex synthesis crystal structure |
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