Viscosity measurements with a magnetoviscometer in the zero-shear and transition region of polypropylenes |
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Authors: | M Gahleitner R Sobczak |
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Institution: | (1) Department of Physical Chemistry, Johannes Kepler University, Altenberger Straße 69, A-4040 Linz, Austria |
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Abstract: | Streaming of a non-Newtonian fluid around a sphere is of special importance not only for measuring viscosities with falling spheres, but also for many problems connected with polymer processing. Using the mentioned measuring principle, attention has to be paid to the following points: The sphere is moving in a fluid (melt) of finite extension which requires the application of wall and perhaps end corrections. These are possibly not the same for Newtonian and non-Newtonian fluids. To calculate the viscosity with the help of Stokes law the steady-state velocity is necessary, and it is essential, how long it takes the sphere to reach it. To compare our results with other data, an average shear rate has to be calculated, since there is no uniform shear rate around the sphere. Velocities being very low in our experiments result in very small Reynolds numbers (Re < 10–3), which allows the application of Stokes law practically without corrections.The experiments were performed at zero shear and in the transition region above. It turned out, that it is usually not possible to extrapolate from shear-dependent viscosity data to zero-shear viscosity.Dedicated to Prof. A. Neckel on the occasion of his 60th birthday |
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Keywords: | Magnetoviscometer zero-shear region transition region start-up wall effects averageshear rate |
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