Impedance and photoadmittance of a passive iron electrode in alkaline sodium sulfide solutions |
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Authors: | Z A Rotenberg T V Martynova V V Batrakov |
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Institution: | (1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 117071 Moscow, Russia;(2) Moscow Pedagogical University, ul. Radio 10a, 05007 Moscow, Russia |
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Abstract: | The intensity-modulated photocurrents (photoadmittance) and the electrochemical impedance of an anodically oxidized iron electrode
are studied in alkaline solutions containing the sulfide ion. The photooxidation of S2- proceeds via a stage of their adsorption. The concentration of S2- adsorbed on the surface decreases at a potential shift in the positive direction |
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