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Impedance and photoadmittance of a passive iron electrode in alkaline sodium sulfide solutions
Authors:Z A Rotenberg  T V Martynova  V V Batrakov
Institution:(1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 117071 Moscow, Russia;(2) Moscow Pedagogical University, ul. Radio 10a, 05007 Moscow, Russia
Abstract:The intensity-modulated photocurrents (photoadmittance) and the electrochemical impedance of an anodically oxidized iron electrode are studied in alkaline solutions containing the sulfide ion. The photooxidation of S2- proceeds via a stage of their adsorption. The concentration of S2- adsorbed on the surface decreases at a potential shift in the positive direction
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