| 无机胶体法制备Pt/C催化剂及其性能表征 |
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| 引用本文： | 徐燕,田建华,张灿,单忠强.无机胶体法制备Pt/C催化剂及其性能表征[J].无机化学学报,2005,21(10):1475-1478. |
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| 作者姓名： | 徐燕 田建华 张灿 单忠强 |
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| 作者单位： | 天津大学化工学院,天津,300072 |
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| 基金项目： | 天津市科技攻关重点资助项目(No.033183111) |
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| 摘 要： | 采用无机胶体法制备用于质子交换膜燃料电池(PEMFC)的Pt/C催化剂。研究了影响PtO2胶体生成和稳定性的因素(溶液的pH值、浓度和温度条件等)以及不同还原剂浓度对Pt/C催化剂性能的影响。透射电子显微镜测试结果表明，采用经优化的工艺条件所制备的Pt/C催化剂平均粒径为3 nm，且分散性好、粒度均匀。X-射线衍射分析表明，催化剂中Pt(111)晶面的相对含量较高，有利于加速氧还原反应。单体PEMFC的电压/电流密度曲线测试表明，所制备的Pt/C催化剂具有良好的电化学性能。
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| 关 键 词： | 质子交换膜燃料电池 Pt/C催化剂 无机胶体法 电化学性能 |
| 文章编号： | 1001-4861(2005)10-1475-04 |
| 收稿时间： | 2005-03-13 |
| 修稿时间： | 2005-05-17 |
Preparation by Inorganic Colloid Method and Characterization of Pt/C Catalysts |
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| XU Yan,TIAN Jian-Hu,ZHANG Can and SHAN Zhong-Qiang.Preparation by Inorganic Colloid Method and Characterization of Pt/C Catalysts[J].Chinese Journal of Inorganic Chemistry,2005,21(10):1475-1478. |
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| Authors: | XU Yan TIAN Jian-Hu ZHANG Can and SHAN Zhong-Qiang |
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| Institution: | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072,School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072,School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 and School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 |
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| Abstract: | Supported Pt / C catalysts used in proton exchange membrane fuel cells (PEMFC) were prepared by the inorganic colloid method. The influences of pH value, concentration and temperature of solutions on the formation and stability of the PtO2 colloid were studied. The performances of Pt / C catalysts prepared with different concentrations of HCHO reducing agents were analyzed. Transmission electron microscopy (TEM) results showed that the Pt / C catalyst with 3 nm platinum crystallites, a higher dispersion and a very narrow size distribution was achieved at optimal conditions. X-ray diffraction (XRD) analysis showed that the relative content of the Pt(111) crystal face in the prepared Pt / C catalyst was increased, and this benefits the acceleration of the oxygen reduction reaction in PEMFC. The measurement results of I~E characteristics of a single PEMFC indicated that the Pt / C catalyst prepared in this work exhibited better electrochemical performance. |
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| Keywords: | Proton exchange membrane fuel cell (PEMFC) Pt / C catalysts Inorganic colloid method Electrochemical performance |
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