| 手性芳基邻二醇的不对称合成 |
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| 引用本文： | 刘湘,潘争光,许建和.手性芳基邻二醇的不对称合成[J].化学进展,2011(5):903-913. |
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| 作者姓名： | 刘湘 潘争光 许建和 |
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| 作者单位： | 江南大学化学与材料工程学院;华东理工大学生物反应器工程国家重点实验室; |
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| 基金项目： | 国家自然科学基金项目(No.20672037); 国家重点实验室专项经费(No.2060204)资助 |
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| 摘 要： | 具有特定功能基团的手性芳基邻二醇是许多具有特殊功能的药物、农药和信息素的重要中间体,近年来手性芳基邻二醇类化合物的合成与应用研究引起了人们的广泛关注.本文从生物催化不对称合成和化学催化不对称合成两方面综述了近年来手性芳基邻二醇的合成进展,概述了前手性底物上取代基的电子效应和空间效应、手性催化剂的种类和反应体系等因素对合...
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| 关 键 词： | 手性芳基邻二醇 不对称合成 生物催化 化学催化 |
Asymmetric Synthesis of Chiral Aryl Vicinal Diols |
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| Liu Xiang Pan Zhengguang Xu Jianhe.Asymmetric Synthesis of Chiral Aryl Vicinal Diols[J].Progress in Chemistry,2011(5):903-913. |
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| Authors: | Liu Xiang Pan Zhengguang Xu Jianhe |
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| Institution: | Liu Xiang1** Pan Zhengguang1 Xu Jianhe2**(1.School of Chemical and Material Engineering,Jiangnan University,Wuxi 214122,China,2.State Key Laboratory of Bioreactor Engineering,East China University of Science and Technology,Shanghai 200237,China) |
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| Abstract: | Chiral aryl vicinal diols with special functional group are potentially valuable synthetic intermediates for the preparation of pharmaceuticals,agrochemicals and pheromones.In recent years,the synthesis and application of chiral aryl vicinal diols have attracted intensive attention of chemists.Recent progress in asymmetric synthesis of chiral aryl vicinal diols is reviewed in both biocatalytic and chemocatalytic perspectives.The effects of some factors,including the electronic effects and steric factors of ... |
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| Keywords: | chiral aryl vicinal diols asymmetric synthesis biocatalysis chemocatalysis |
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