Copper‐Catalyzed Aerobic Oxidative Reaction of Sulfonyl Hydrazides with Alcohols: An Easy Access to Sulfinates |
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| Authors: | Bingnan Du Zan Li Ping Qian Dr. Jianlin Han Prof. Dr. Yi Pan |
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| Affiliation: | 1. School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China;2. MaAnShan High-Tech Research Institute of, Nanjing University, MaAnShan, P. R. China |
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| Abstract: | ![]()
A Cu‐catalyzed aerobic oxidative reaction between sulfonyl hydrazides and alcohols has been developed. In this reaction, sulfonyl hydrazides act as the sulfinic acid precursors to react with alcohols, resulting in sulfinic esters with up to 72 % yield. This catalytic system tolerates a wide range of sulfonyl hydrazide substrates, and represents a new strategy for the transformation of readily available sulfonyl hydrazides. |
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| Keywords: | Aerobic catalysis copper oxidative sulfonyl hydrazides |
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