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Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties
Authors:Maeda Hiromitsu  Hasegawa Masahiro  Hashimoto Takashi  Kakimoto Takuya  Nishio Satoru  Nakanishi Takashi
Institution:Department of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu 525-8577, Japan. maedahir@se.ritsumei.ac.jp
Abstract:Phenylethynyl-bridged dipyrrin "dimers" have performed ZnII complexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and "golf ball"-like architectures, were observed.
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