Lewis acid catalysis in heterolysis reactions of glycol ether radicals mimicking diol dehydratase-catalyzed reactions |
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| Authors: | Miranda Neil Xu Libin Newcomb Martin |
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| Institution: | Department of Chemistry, University of Illinois at Chicago, 845 W. Taylor Street, Chicago, IL 60607, USA. |
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| Abstract: | Zinc bromide-catalyzed heterolysis reactions of glycol ether radicals were studied by laser flash photolysis methods, which gave the binding constants and catalytic rate constants for fragmentation. The Lewis acid-catalyzed heterolysis reactions mimic a putative reaction pathway in diol dehydratase-catalyzed reactions and are potentially useful polar processes for incorporation into conventional radical chain reaction sequences. reaction: see text] |
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