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Preparation of nanometer FeCuP alloy and its application in decomposition of PH3
作者姓名:Chang  Xiu  Han  Ji  Li  Ren  Xue  Jiao  Tang  Bao  Gui  Zhang
作者单位:College of Environmental Science & Engineering, Nankai University, Tianjin 300071, China
摘    要:A new ternary Fe-based alloy catalyst FeCuP applied to decompose PH_3 was prepared with low-cost material by chemical reduction deposition method.The properties of it were characterized by XRD,ICP and SEM.Its catalytic activity on the decomposition of PH_3 and the decomposition conditions were studied.FeCuP alloy exhibits high thermal stabilities and high catalytic activity.Using it as catalyst,the decomposition temperature of phosphine decreases from over 800℃to 400-500℃.The decomposition rate of phosphine achieved 100%.

关 键 词:FeCuP合金  催化剂  磷化氢  分解方法
收稿时间:13 March 2007
修稿时间:2007-03-13

Preparation of nanometer FeCuP alloy and its application in decomposition of PH3
Chang Xiu Han Ji Li Ren Xue Jiao Tang Bao Gui Zhang.Preparation of nanometer FeCuP alloy and its application in decomposition of PH3[J].Chinese Chemical Letters,2007,18(10):1285-1288.
Authors:Chang Xiu Han  Ji Li Ren  Xue Jiao Tang  Bao Gui Zhang
Institution:College of Environmental Science & Engineering, Nankai University, Tianjin 300071, China
Abstract:A new ternary Fe-based alloy catalyst FeCuP applied to decompose PH3 was prepared with low-cost material by chemical reduction deposition method. The properties of it were characterized by XRD, ICP and SEM. Its catalytic activity on the decomposition of PH3 and the decomposition conditions were studied. FeCuP alloy exhibits high thermal stabilities and high catalytic activity. Using it as catalyst, the decomposition temperature of phosphine decreases from over 800 °C to 400–500 °C. The decomposition rate of phosphine achieved 100%.
Keywords:FeCuP alloy  Catalysts  Decomposition  Phosphine
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