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Tri(t-butyl)phosphine-assisted selective hydrosilylation of terminal alkynes |
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| Authors: | Wei Wu Xiao Yun Zhang Shou Xing Kang Yan Min Gao |
| Affiliation: | Department of Chemistry, China University of Petroleum(East China), Qingdao 266555, China |
| Abstract: | A highly efficient and regio-/stereoselective method of hydrosilylating terminal alkynes was developed using Pt(DVDS)-tri(t-butyl) phosphine catalyst system at room temperature.Trans-products or alpha-products were obtained almost exclusively depending on the alkynes and silanes employed. |
| Keywords: | Hydrosilylation Terminal alkynes Tri(t-butyl)phosphine Platinum |
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