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Permanent dipole moments and multi-photon resonances
Authors:Mary Ann Kmetic  William J. Meath
Affiliation:Department of Chemistry, University of Western Ontario, London, Canada
Abstract:The effects of non-zero diagonal dipole matrix elements on multi-photon resonance profiles, for the interaction of molecules with a sinusoidal field, are discussed by using an expression for the profiles derived in the rotating wave approximation. The validity of this result is discussed with reference to exact two-level model calculations.
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