Understanding the synergistic effect of mixed solvent annealing on perovskite film formation |
| |
Institution: | 1.School of Physics and Astronomy and Collaborative Innovation Center of IFSA(CICIFSA), Shanghai Jiao Tong University, Shanghai 200240, China;2.Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;3.State Key Laboratory of Fluorinated Materials, Zibo 256401, China |
| |
Abstract: | Morphology control of perovskite films is of critical importance for high-performance photovoltaic devices. Although solvent vapor annealing (SVA) treatment has been widely used to improve the film quality efficiently, the detailed mechanism of film growth is still under construction, and there is still no consensus on the selection of solvents and volume for further optimization. Here, a series of solvents (DMF, DMSO, mixed DMF/DMSO) were opted for exploring their impact on fundamental structural and physical properties of perovskite films and the performance of corresponding devices. Mixed solvent SVA treatment resulted in unique benefits that integrated the advantages of each solvent, generating a champion device efficiency of 19.76% with improved humidity and thermal stability. The crystallization mechanism was constructed by conducting grazing-incidence wide-angle x-ray diffraction (GIWAXS) characterizations, showing that dissolution and recrystallization dominated the film formation. A proper choice of solvent and its volume balancing the two processes thus afforded the desired perovskite film. This study reveals the underlying process of film formation, paving the way to producing energy-harvesting materials in a controlled manner towards energy-efficient and stable perovskite-based devices. |
| |
Keywords: | perovskite solar cell solvent vapor annealing dissolution recrystallization |
|
| 点击此处可从《中国物理 B》浏览原始摘要信息 |
| 点击此处可从《中国物理 B》下载免费的PDF全文 |
|