| LiYF4晶体中Ho3+离子真空紫外吸收光谱的理论解析 |
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| 引用本文： | 李彩云,王永明.LiYF4晶体中Ho3+离子真空紫外吸收光谱的理论解析[J].无机化学学报,2013,29(4):735-738. |
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| 作者姓名： | 李彩云 王永明 |
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| 作者单位： | 武警学院基础部, 廊坊 065000;武警学院基础部, 廊坊 065000 |
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| 摘 要： | 运用配位场理论方法获得了Ho3+离子低自旋4f95d组态的谱项和J-光谱多重态,根据电偶极跃迁选律合理地解析了LiYF4晶体中Ho3+离子在真空紫外区(120～160 nm)的吸收光谱,4个主要的吸收峰分别被归属为从基态(5I8)到Ho3+离子的低自旋4f95d组态的自旋允许跃迁。
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| 关 键 词： | LiYF4晶体 Ho3+离子 VUV吸收光谱 理论分析 |
| 收稿时间： | 2012/10/19 0:00:00 |
| 修稿时间： | 2012/11/27 0:00:00 |
Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho3+ Doped in LiYF4 Crystal |
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| LI Cai-Yun and WANG Yong-Ming.Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho3+ Doped in LiYF4 Crystal[J].Chinese Journal of Inorganic Chemistry,2013,29(4):735-738. |
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| Authors: | LI Cai-Yun and WANG Yong-Ming |
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| Institution: | Department of Basic Course, the Armed Police Academy, Langfang, Hebei 065000, China;Department of Basic Course, the Armed Police Academy, Langfang, Hebei 065000, China |
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| Abstract: | Spectral terms and J-spectral multiplet of low-spin 4f95d configuration of Ho3+ were obtained with the method of ligand field theory. According to the selection rules for dipole transitions, the absorption spectra of Ho3+ doped in LiYF4 in vacuum ultraviolet region (120~160 nm) of the spectrum were theoretically interpreted by applying the crystal field model, and the four main bands were assigned to the spin-allowed transitions from the ground state (5I8) to J-spectral multiplet of low-spin 4f95d configuration of Ho3+ ion. |
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| Keywords: | LiYF4 crystal Ho3+ ion VUV absorption spectra theoretical analysis |
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