Thermoanalytical and spectroscopic studies on hydrazinium lighter lanthanide complexes of 2-pyrazinecarboxylic acid |
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Authors: | Thathan Premkumar Subbiah Govindarajan |
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Institution: | (1) Department of Chemistry, Bharathiar University, Coimbatore, 641046, India;(2) Present address: Department of Materials Science and Engineering, Gwangju Institute of Science and Technology, 1 Oryong-dong, Buk-gu, Gwangju, 500-712, South Korea |
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Abstract: | The new hydrazinium lanthanide metal complexes of 2-pyrazinecarboxylic acid (HpyzCOO) of the formulae (N2H5)2Ln(pyzCOO)5] · 2H2O (1), where Ln = La or Ce and (N2H5)3Ln(pyzCOO)4(H2O)] · 2NO3 (2), where Ln = Pr, Nd, Sm or Dy have been synthesized and characterized by physico-chemical methods. The IR absorption bands
of N–N stretching at 960 cm−1 unambiguously prove the existence of N2H5
+ ions. The bonding parameters β, b1/2, % δ and η, have been calculated from the electronic spectroscopic (hypersensitive) bands of Pr(III) and Nd(III) complexes.
All the complexes undergo endothermic followed by exothermic decomposition to leave the respective metal oxides as the end
products. However, the DTA of the complexes 2 demonstrate rather sharp peak than the complexes 1, owing to overwhelming exothermicity, which may be due to the loss of both hydrazine and nitrate moieties in the same step.
The X-ray powder diffraction studies reveal the existence of isomorphism among the member complexes. |
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