| Synthesis and Absorption Properties of Calix[6]amides—based Polymers |
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| 作者姓名： | FaFuYANG HongYuGUO JianRongLIN YuanYinCHEN |
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| 作者单位： | [1]DepartmentofChemistry,FujianNormalUniversity,Fuzhou350007 [2]DepartmentofChemistry,WuhanUniversity,Wuhan430072 |
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| 基金项目： | 国家自然科学基金，国家自然科学基金 |
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| 摘 要： | Reacting calix6]arene hexaesters with poly(ethyleneimine),a series of calix6]amidesbased polymers were obtained for the first time.It is found that they show high absorption capacities towards soft cations comparing to hard cations,and the absorption abilities enhanced with the increasing of calixarene content,which may indicates the cavity of calixarene plays crucial role in absorption.Polymer 2c shows good selective absorption capability towards Ag^ among the tested cations.
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| 关 键 词： | 杯[6]芳烃 氨基化合物 聚合物 合成 吸收 阳离子 银离子 |
Synthesis and Absorption Properties of Calix[6]amides-based Polymers |
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| FaFuYANG HongYuGUO JianRongLIN YuanYinCHEN.Synthesis and Absorption Properties of Calix[6]amides-based Polymers[J].Chinese Chemical Letters,2003,14(5):453-455. |
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| Authors: | Fa Fu YANG Hong Yu GUO Jian Rong LIN Yuan Yin CHEN |
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| Abstract: | Reacting calix6]arene hexaesters with poly(ethyleneimine), a series of calix 6]amides- based polymers were obtained for the first time. It is found that they show high absorption capacities towards soft cations comparing to hard cations, and the absorption abilities enhanced with the increasing of calixarene content, which may indicates the cavity of calixarene plays crucial role in absorption. Polymer 2c shows good selective absorption capability towards Ag+ among the tested cations. |
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| Keywords: | Calix[6]arene polymer absorption |
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