Dielectric relaxation in polymeric solids Part 1. A new model for the interpretation of the shape of the dielectric relaxation function

A model is proposed which explains the shape of the dielectric relaxation function at the glass transition of polymers. The model is based on the idea that the molecular mobility at the glass transition is controlled by intra- and intermolecular interaction. In addition, a specific model for the local chain dynamics in amorphous polymer systems is used. According to the scaling hypothesis of molecular dynamics the model relates the high frequency dependence of the dielectric loss curve to the local chain dynamics and the low frequency dependence to the intermolecular correlation.