Microporous and mesoporous 8YSZ materials derived from polymeric acetylacetone-modified precursors for inorganic membrane applications |
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Authors: | GJW van der Donk WA Meulenberg |
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Institution: | a Forschungszentrum Jülich GmbH (IEF-1), Zentralbibliothek, Mrs. Specht, Leo Brandt Strasse, D-52425 Jülich, Germany b Instituto de Tecnología Química (UPV-CSIC), Av. Los naranjos s/n, E-46022 Valencia, Spain |
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Abstract: | Both microporous and mesoporous 8% mol-yttria-stabilized zirconia (8YSZ) material can be prepared from the same 8YSZ sols. Stable 8YSZ sols with particle sizes smaller than 10 nm were prepared by using acetylacetone as a precursor modifier in combination with carboxylic acids. Nonanic and caproic acids are preferred due to their higher stability in combinations of highly concentrated sols. Cubic 8YSZ microporous material can be prepared by using acetylacetone as a precursor modifier with caproic acid as the catalyst. These materials can be transformed into mesoporous material composed of crystalline primary cubic YSZ nanoparticles by simply mixing with structure-directing agents. Use of the block copolymer F127 resulted in the largest specific surface area of 100 m2/g. Thin 8YSZ layers of these sols can be prepared on glass slips and on graded porous alumina supports with thicknesses between 20 and 100 nm. |
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Keywords: | 81 10 &minus h 64 60 Q&minus 81 20 Fw 82 45 Mp 65 80 +n 83 80 Hj |
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