Inclusion of Two PhP(O)(OH)
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Guest Molecules into the Cavity of Macrocyclic Cavidand Cucurbit[8]uril |
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| Authors: | Elena V Chubarova Denis G Samsonenko Maxim N Sokolov Olga A Gerasko Vladimir P Fedin Javier G Platas |
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| Institution: | 1. Siberian Branch of the Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, Academician Lavrentiev Avenue 3, Novosibirsk, 630090, Russia
2. University of La Laguna, 38200, Tenerife, Canary Islands, Spain
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| Abstract: | A new inclusion compound which is a supramolecular adduct of cucurbit8]uril with two guest molecules of phenylphosphonic acid, PhP(O)(OH)2, included into the cavity as ``two guests in host'' is reported. The guests match both size and hydrophilicity/hydrophobicity requirements. Two phenyl groups of molecules of PhP(O)(OH)2 are directed toward the center of the large hydrophobic cavity whereas the PO(OH)2 groups are outward-looking and bound with each hydrophilic portal of cucurbit8]uril by a short hydrogen bond. |
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