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Syntheses and structures of five cadmium(II) coordination polymers from 1,2-bis(1,2,4-triazol-1-yl)ethane |
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| Authors: | Baolong Li Xia Zhu Junhui Zhou Yanfen Peng Yong Zhang |
| Affiliation: | aCollege of Chemistry and Chemical Engineering, Key Laboratory of the Organic Synthesis of Jiangsu Province, Suzhou University, Street Shizi No. 1, Suzhou 215006, PR China bState Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China |
| Abstract: | Five structually distinct coordination polymers [Cd(bte)3](NO3)2 n (1), [Cd(bte)2(H2O)2](NO3)2 n (2), [Cd(bte)(NO2)2] n (3), [Cd(bte)2(H2O)2](H2O)2(ClO4)2 n (4) and [Cd(bte)(NCS)2]n (5) (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane) have been synthesized and characterized. The structures of 1, 2, 3, 4 and 5 consist of a double interpenetrating three-dimensional -poloniumn cubic network, a two-dimensional (4,4) network, a two-dimensional rhombic network, a one-dimensional double chain containing 18-membered [Cd2(bte)2] rings and a two-dimensional rhombic network containing eight-membered [Cd2(SCN)2] rings, respectively. |
| Keywords: | Cadmium complex Bis(triazole) ligand Crystal structure Anion role |
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