| A Three-dimensional Heteronuclear Polymer of [Ag2Fe（SCN）5（DMF）]n Containing Channels and One-dimensional Ag2S2-S-Ag2S2 Chains with Ag…Ag Interaction |
| |
| 引用本文： | 李秀玲,赵长春,陈久桐,杜文新.A Three-dimensional Heteronuclear Polymer of [Ag2Fe（SCN）5（DMF）]n Containing Channels and One-dimensional Ag2S2-S-Ag2S2 Chains with Ag…Ag Interaction[J].中国化学,2004,22(6):533-536. |
| |
| 作者姓名： | 李秀玲 赵长春 陈久桐 杜文新 |
| |
| 作者单位： | Department of Chemistry，Xuzhou Normal University，Xuzhou，Jiangsu 221116，China，Department of Chemistry，Xuzhou Normal University，Xuzhou，Jiangsu 221116，China，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
| |
| 摘 要： | Introduction So far, considerable attention has been paid to mag-netic interaction between two different metal ions.1-3 As a potential bridging ligand, thiocyanate can coordinate to a harder metal center with N atom and softer ones with S atom at the same time, resulting in the formation of small ferromagnetic coupling.2 On the other hand, the Fe(III) atom is a good candidate as a hard acid and Ag(I) is a good candidate as a soft acid, so that the Fe(III) centers could be expected to conn…
|
| 关 键 词： | 异核核糖核酸聚合物 银…银交互作用 银离子 晶体结构 硫氰酸桥 一维链 三维链 |
A three‐dimensional heteronuclear polymer of [Ag2Fe(SCN)5‐(DMF)]n containing channels and one‐dimensional Ag2S2‐S‐Ag2S2 chains with Ag…Ag interaction |
| |
| LI,Xiu-Ling,a ZHAO,Chang-Chuna CHEN,Jiu-TongbDU,Wen-Xinb.A three‐dimensional heteronuclear polymer of [Ag2Fe(SCN)5‐(DMF)]n containing channels and one‐dimensional Ag2S2‐S‐Ag2S2 chains with Ag…Ag interaction[J].Chinese Journal of Chemistry,2004,22(6):533-536. |
| |
| Authors: | LI Xiu-Ling a ZHAO Chang-Chuna CHEN Jiu-TongbDU Wen-Xinb |
| |
| Institution: | LI,Xiu-Ling*,a ZHAO,Chang-Chuna CHEN,Jiu-TongbDU,Wen-Xinb |
| |
| Abstract: | The Ag2S2 rings connect Fe(NCS)5(DMF)]2‐ (DMF=N,N‐dimethylformamide) octahedrons by bridging thiocyanates leading to a 3‐D Ag2Fe(SCN)5(DMF)]n framework. The Fe(III) atoms are in the octahedral geometry and Ag(1) atoms are in the distoned tetrahedral geometry. One‐dimensional Ag2S2‐S‐Ag2S2 wave‐like strand chains along the b‐axis and channels constructed from ten‐membered Ag2Fe(SCN)2S rings along the c‐axis feature the three‐dimensional framework. The Ag…Ag distance of 0.3103(1) nrn in Ag2S2 rings indicates weak Ag…Ag interaction. Such an Ag2S2‐S‐Ag2S2 chain in silver(I) complexes is unprecedented. Crystal data: M,=635.09, ortho‐rhombic, Pnma, a= 1.64214(13) nm, b= 1.40075(11) nm, c=0.84445(7) nm, V=1.9424(3) nm3, Z=4, μ(Mo Kα) =3.278 mm?1, Dcaled=2.172g × cm?3. F(000)= 1220, R1=0.0443, wR2=0.1138. |
| |
| Keywords: | silver(I)‐iron(III) heteronuclear polymer crystal structure thiocyanate bridge one‐dimensional chain Ag…Ag interaction |
| 本文献已被 CNKI 等数据库收录！ |
|
