Interaction of hydrosilanes with carbon dioxide and secondary amines or silylamines |
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| Authors: | A D Kirilin A A Dokuchaev I N Menchaikina E V Semenova N B Sokova E A Chernyshev |
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| Institution: | (1) M. V. Lomonosov Moscow State Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571 Moscow, Russian Federation |
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| Abstract: | The reaction of hydrosilanes with carbon dioxide and secondary amines or silylamines was studied for the first time. The dependence of the composition and the structure of the products obtained on the nature of the reagents and on the reaction conditions was found. The hydrosilane-carbon dioxide system, unknown previously, can be used as anN-siloxycarbonylating reagent in the synthesis ofO-silylurethanes. A scheme for the formation ofO-silylurethanes was proposed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2309–2312, September, 1996. |
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| Keywords: | hydrosilanes amines N-siloxycarbonylation carbon dioxide O-silylurethanes synthesis hexamethyldisilazane |
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