| 基于树形链转移剂的可逆加成断裂链转移聚合 |
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| 引用本文： | 邵立东,胡敏奇,马琴,徐立,陈林,毕韵梅.基于树形链转移剂的可逆加成断裂链转移聚合[J].化学通报,2011,74(1):16-23. |
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| 作者姓名： | 邵立东 胡敏奇 马琴 徐立 陈林 毕韵梅 |
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| 作者单位： | 云南师范大学化学化工学院,昆明,650092 |
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| 基金项目： | 国家自然科学基金，云南省社会发展科技计划应用基础研究专项面上项目 |
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| 摘 要： | 可逆加成断裂链转移(RAFT)聚合是最近十多年来发展起来的一种活性/可控技术,链转移剂(CTA)为该技术的核心.本文介绍了采用R路径合成法、Z路径合成法合成R核与Z核树形链转移剂以及它们调控不同单体的RAFT聚合,合成树形-线性二嵌段共聚物、树形-线性-树形三嵌段共聚物和树形-星形聚合物等树枝状聚合物的研究进展.
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| 关 键 词： | 可逆加成断裂链转移(RAFT)聚合 树形链转移剂 树形聚合物 |
Reversible Addition-fragmentation Chain Transfer Polymerization Mediated by Dendritic Chain Transfer Agents |
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| Shao Lidong,Hu Minqi,Ma Qin,Xu Li,Chen Lin,Bi Yunmei.Reversible Addition-fragmentation Chain Transfer Polymerization Mediated by Dendritic Chain Transfer Agents[J].Chemistry,2011,74(1):16-23. |
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| Authors: | Shao Lidong Hu Minqi Ma Qin Xu Li Chen Lin Bi Yunmei |
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| Institution: | Shao Lidong,Hu Minqi,Ma Qin,Xu Li,Chen Lin,Bi Yunmei*(College of Chemistry and Chemical Engineering,Yunnan Normal University,Kunming 650092) |
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| Abstract: | Reversible addition-fragmentation chain transfer(RAFT) polymerization is a living /controlled polymerization technique emerged over the last ten years.Chain transfer agents(CTAs) play a key role in the polymerization.In this paper,synthetic methods of R-core and Z-core dendritic CTAs by R-route and Z-route,and RAFT polymerization of different monomers mediated by these dendritic CTAs were introduced.The dendritic polymers including dendritic-linear diblock polymers,dendritic-linear-dendritic triblock polyme... |
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| Keywords: | Reversible addition-fragmentation chain transfer(RAFT) polymerization Dendritic chain transfer agents Dendritic polymers |
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