(1) Inistitito de Qufmica Fisica Rocasolano, CSIC, Serrano, 28006 Madrid, Spain;(2) Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland, 21250, U.S.A.
Abstract:
Despite their seeming simplicity, substituted guanidines have not particularly caught the attention of the thermochemical community. The current paper compares the enthalpy of formation of solid substituted guanidines with correspondingly substituted benzenes, also as solids.