Easily immobilized di- and tetraphosphine linkers: rigid scaffolds that prevent interactions of metal complexes with oxide supports |
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Authors: | Yang Yuan Beele Björn Blümel Janet |
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Institution: | Chemistry Department, University of Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany. |
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Abstract: | Di- and tetraphosphines with rigid phenyl-, biphenyl-, and tetraphenylstannane, -silane, and -methane scaffolds, and various substituents R, have been synthesized and immobilized via triethoxysilane-propagated formation of one or two surface-bound phosphonium moieties. The remaining phosphine groups can be coordinated to metal complexes. All the detective work and proof is done by solid-state NMR spectroscopy. |
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