| 手性金属簇合物的合成、结构表征及其反应 |
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| 引用本文： | 丁二润,吴树林,李庆山,殷元骐. 手性金属簇合物的合成、结构表征及其反应[J]. 物理化学学报, 1999, 15(3): 241-246. DOI: 10.3866/PKU.WHXB19990309 |
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| 作者姓名： | 丁二润 吴树林 李庆山 殷元骐 |
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| 作者单位： | State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000 |
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| 摘 要： | 用潜手性羰基簇合物 ( μ3 S)RuCo2 (CO) 9( 1 )与阴离子金属交换试剂Na[M (CO) 3C5 H4C(O)R][R =H ,CH3,C6 H5 ,C6 H4C(O)OCH3;M =Mo ,W ]在四氢呋喃中回流反应 ,生成一系列新的由四个不同原子组成的不对称四面体簇合物 ( μ3 S)RuCoM (CO ) 8CpCOR .研究了簇合物 ( μ3 S)RuCoMo(CO) 8CpCOCH3的还原反应 .对合成的所有化合物进行了IR、1HNMR、C/H元素分析 ,测定了簇合物( μ3 S)RuCoMo(CO) 8CpCOC6 H5 的单晶结构 .
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| 关 键 词： | 过渡金属 簇合物 晶体结构 |
| 收稿时间： | 1998-05-04 |
| 修稿时间： | 1998-10-05 |
Synthesis, Structural Characterization and Reaction of the Chiral Clusters |
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| Ding Errun,Wu Shulin,Li Qingshan,Yin Yuanqi. Synthesis, Structural Characterization and Reaction of the Chiral Clusters[J]. Acta Physico-Chimica Sinica, 1999, 15(3): 241-246. DOI: 10.3866/PKU.WHXB19990309 |
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| Authors: | Ding Errun Wu Shulin Li Qingshan Yin Yuanqi |
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| Affiliation: | State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000 |
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| Abstract: | Several chiral clusters RuCoMo(μ-3 S)(CO) 8C 5H 4C(O)R were synthesized by the thermal reaction of the precursor (μ-3 S)RuCo2(CO) 9 with functionally substituted cyclopentadienyl tricarbonyl metal complex anions [M(CO) 3(η5-C5H4)C(O)R] -(R=H,CH3,C6H5,C 6H 4C(O)OCH 3;M=Mo,W)in THF. All of these clusters were characterized by C/H elemental analysis, IR and 1H NMR. Crystal structure of the cluster (μ-3 S)RuCoMo(CO)8CpCOC6H5 has also been solved by single crystal X ray diffraction. |
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| Keywords: | Transition metal Cluster Crystal structure |
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