Voltammetric study of copper(I) thioacetamide complexes |
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Authors: | Hao-Ming Jeng Chung-Zen Tsai and Tsu-Yen Chang |
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Institution: | (1) Materials Research Laboratories, Industrial Technology Research Institute, 31035 Chu Tung, Hsin Chu, Taiwan, Republic of China |
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Abstract: | Summary The composition and stability of copper(I) complexes with thioacetamide (TAA) have been evaluated with the help of square-wave voltammetry using the fast pulse technique. Two species, namely Cu(I) (TAA) and Cu(I) (TAA)2, have been identified having the formation constants log 1=16.85; log 2=18.03. The complex is stable in highly acidic medium (pH1). The application for the determination of copper is pointed out. |
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