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New theoretical analysis ofv 2 0→1Q-bands of ammonia
Authors:S. Marchetti  M. Dilonardo
Affiliation:(1) Centro Ricerche Energia-Frascati, Comitato Nazionale per la Ricerca e per lo Sviluppo dell’Energia Nucleare e delle Energie Allernative (ENEA), 00044 Frascati, C.P. 65, Roma, Italia;(2) Centro Studio per la Chimica dei Plasmi del C.N.R., Via Amendola 173, 70126 Bari, Italia
Abstract:
Summary The analysis ofQ-band infra-red transitionsv 20→1 of ammonia has been performed by using existing data and a simple polynomial expansion up to the tenth order ofJ andK. The lines withK=3 require an additionalJ-dependent term because of theK-splitting effect. In this manner, the spectrum has been reproduced within the accuracy of the experimental data. New experimental lines withJ≦20 have been reported or assigned. To speed up publication, the authors of this paper have agreed to not receive the proofs for correction.
Keywords:Calculation of molecular spectra
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