The 'Trinity' helix: synthesis and structural characterisation of a C3-symmetric tris-bidentate ligand and its coordination to Ag(I) |
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Authors: | Conerney Brian Jensen Paul Kruger Paul E MacGloinn Conchúir |
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Institution: | Department of Chemistry, Trinity College, Dublin 2, Ireland. |
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Abstract: | The synthesis and structural characterisation of a novel C3-symmetric tris-bidentate ligand, L, featuring a triphenylamine core appended by pyridylimine coordination sites is reported: 1H NMR compleximetric titration studies with Ag(I) and ESMS indicate the presence of Ag3L2]3+ species in solution, consistent with the formation of a trinuclear double helicate complex: the Trinity helix. |
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