Large reaction radii for the quenching of fluorescent excited states of liquid cis-decalin and cyclohexane |
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| Authors: | L.H. Luthjens H.D.K. Codee H.C. de Leng A. Hummel |
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| Affiliation: | Interuniversitair Reactor Instituut, 2629 JB Delft, The Netherlands |
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| Abstract: | ![]()
The large rates of quenching by different solutes of the fluorescent solvent excited state in liquid cis-decalin and cyclohexane as observed by pulse radiolysis are explained by large reaction radii. Values of 14, 13, and 15 Å are found for the quenching of the excited state in cis-decalin by CCl4, in cyclohexane by CCl4, and by O2 respectively. |
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