Synthesis and crystal structure of a novel mixed valence tri-iron complex salt: [hexakis(thiazole)iron(II)][μ-oxo- bis(trichloroiron(III))] |
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| Authors: | Michael James Hiroyuki Kawaguchi and Kazuyuki Tatsumi |
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| Institution: | Department of Chemistry, Faculty of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-01, Japan |
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| Abstract: | The title compound, Fe(tz)6]Fe2OCl6] (1) (tz = thiazole) has been synthesized under argon by the reaction of anhydrous FeCl3 with thiazole in ethanol. 1 crystallises in the cubic space group 
(no. 205) with a = 15.001(5) Å, V = 3375(2) Å3, Z = 4, R = 0.061 and Rw = 0.073. 1 consists of a face-centered cubic array of Fe(tz)6]2 cations, with the oxo-bridged Fe2OCl6]2? anion occupying the cell and edge centres. |
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| Keywords: | mixed valence oxo-bridged face-centred cubic tri-metallic |
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