The reaction of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate with fullerene C60期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

按检索

The reaction of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate with fullerene C60

Authors:	N F Gol'dshleger A S Astakhova A S Lobach G N Boiko N N Denisov V A Nadtochenko O S Roshchupkina Yu M Shul'ga

Institution:	(1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation;(2) Institute of Structural Macrokinetics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation

Abstract:	Heating (100 °C, toluene) or photolysis (Nd³⁺ : YAG laser, = 532 mil, benzonitrile) of a mixture of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate (Hantsch ester) (1) and fullerene C₆₀ under anaerobic conditions results in the formation of fullerene hydrogenation products and ethyl 2,6-dimethylpyridine-3,5-dicarboxylate, which is the product of dehydrogenation of1, identified by IR spectroscopy and mass spectrometry. The triplet state of C₆₀ is quenched by the Hantsch ester.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2531–2534, October, 1996.

Keywords:	fullerene C₆₀ 1 4-dihydropyridines Hantsch ester dehydrogenation laser photolysis ¹H NMR spectroscopy
本文献已被 SpringerLink 等数据库收录！