Modular construction of dendritic carbosilanes. Organization Of dendrimer connectivity around bifunctional precursors that are adapted for sequential convergent and divergent propagative steps |
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Authors: | Casado Stobart |
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Institution: | Department of Chemistry, University of Victoria, British Columbia, Canada V8W 2Y2. |
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Abstract: | Regiospecific hydrosilylation of 1-bromo-4-(prop-2-enyl)benzene offers an efficient route to molecular building block precursors that can accommodate sequential divergent and convergent steps for dendritic extension, establishing a modular methodology for assembly and organization of connectivity used for synthesis of modified carbosilane dendrimers including 14. |
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