Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes |
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| Authors: | Nguyen Duc Hanh Pérez-Torrente Jesús J Lomba Laura Jiménez M Victoria Lahoz Fernando J Oro Luis A |
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| Affiliation: | Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea - ICQCH, Universidad de Zaragoza-C.S.I.C., 50009-Zaragoza, Spain. |
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| Abstract: | Unsaturated σ,π-cyclooctenyl and hydrido Ir(III) complexes bearing an unusual tridentate dianionic ONO pincer-type ligand have been straightforwardly obtained from 2,6-pyridinedicarboxylic acid and standard Ir(I) starting materials. These complexes efficiently catalyzed the arene C-H borylation under thermal conditions. |
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