Application of N,N‐bis(diphenylphosphino)aniline palladium(II) complexes as pre‐catalysts in Heck coupling reactions |
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| Authors: | Bahattin Gümgüm Nermin Biricik Feyyaz Durap Ismail Özdemir Nevin Gürbüz Wee Han Ang Paul J. Dyson |
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| Affiliation: | 1. Department of Chemistry, University of Dicle, 21280 Diyarbakir, Turkey;2. Department of Chemistry, University of In?nü, 44280 Malatya, Turkey;3. Institut des Sciences et Ingenierie Chimiques, Ecole Polytechnique Federale de Lausanne (EPFL) CH‐1015 Lausanne, Switzerland |
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| Abstract: | Palladium(II) complexes with N,N‐bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre‐catalysts have been determined by single‐crystal X‐ray diffraction. Copyright © 2007 John Wiley & Sons, Ltd. |
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| Keywords: | aminophosphines bis(diphenylphosphino)aniline catalysis Heck reaction N,P ligands palladium complexes X‐ray structure |
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