Synthesis and X-ray structure of p-tolyl phenylthioglyoxylate |
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| Authors: | Stanislaw Boryczka Tadeusz Glowiak Georges Le Guillanton Quang Tho Do Driss Elothmani |
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| Institution: | (1) Department of Organic Chemistry, Silesian School of Medicine, 4 Jagiello ska Str., 41-200 Sosnowiec, Poland;(2) Institut of Chemistry, University of Wroclaw, 14 F.Joliot-Curie Str., 50-383 Wroclaw, Poland;(3) Laboratoire d'Electrochimie Organique (CNRS), Universite Catholique de l'Ouest, BP 808, 49008 Angers 01, France |
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| Abstract: | The title compound (C15H12O2S) is triclinic witha=7.077(10),b=8.825(2),c=11.068(2) Å,  =106.66(3)o, Z=2, and space group P . The significant structural features lies in the two carbonyl groups of the thioglyoxylate which are oriented antiperiplanar to each other –168.2(2)o]. The central C(8)–C(9) bond is 1.553(3) Å. The phenyl rings are twisted with respect to the carbonyl groups. Short contacts are present between S and O(1) 2.652(2) Å] and also between S and O(2) 2.758(2) Å]. |
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| Keywords: |  -oxo-Thioester" target="_blank">gif" alt="agr" align="BASELINE" BORDER="0">-oxo-Thioester thioglyoxylate |
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