| 二(2-苯并咪唑亚甲基)胺合Zn(Ⅱ)配合物晶体和电子 结构研究及生物活性测定 |
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| 引用本文： | 刘小兰,程庆彦,周卫红,赵茹,刘晓红,缪方明.二(2-苯并咪唑亚甲基)胺合Zn(Ⅱ)配合物晶体和电子 结构研究及生物活性测定[J].化学学报,2001,59(7):1045-1053. |
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| 作者姓名： | 刘小兰 程庆彦 周卫红 赵茹 刘晓红 缪方明 |
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| 作者单位： | 天津师范大学化学与生命科学学院 |
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| 基金项目： | 天津市教委重点学科资助项目 |
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| 摘 要： | 合成了二(2-苯并咪唑亚甲基)胺合Zn(Ⅱ)高氯酸盐配合物C16H15N5Zn·(ClO4)2·3H2O和C32H30N10Zn·(ClO4)2·C2H5OH，进行了元素分析、红外和紫外表征。对后者采用X射线方法测定了晶体结构，并采用G94W程序进行了量子化学计算，利用邻苯三酚自氧化法测定了所合成配合物的生物活性。
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| 关 键 词： | 苯并咪唑P 胺P 超氧化物歧化酶 量子化学 锌络合物 晶体结构 电子结构 生物活性 |
| 修稿时间： | 2000年11月21 |
Synthesis, crystal and electronic structure, and activities of zinc complexes of N, N-bis(benzimidazol-2-ylmethyl) amine |
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| Liu Xiaolan,Cheng Qingyan,Zhou Weihong,Zhao Ru,Liu Xiaohong,Miao Fangming.Synthesis, crystal and electronic structure, and activities of zinc complexes of N, N-bis(benzimidazol-2-ylmethyl) amine[J].Acta Chimica Sinica,2001,59(7):1045-1053. |
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| Authors: | Liu Xiaolan Cheng Qingyan Zhou Weihong Zhao Ru Liu Xiaohong Miao Fangming |
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| Abstract: | The complexes of N,N-bis(benzimidazol-2-ylmethyl) amine with zinc (Ⅱ ), C16H15N5Zn·(ClO4)2·3H2O (A) and C32H30N10Zn·(ClO4)2·C2H5OH (B), were synthesized and characterized with element analysis, UV, and IR spectroscopy. The crystal structure of (B) was determined by X-ray diffraction. Quantum chemistry computation was also performed on the these compounds using G94W program. Biological activities of the complexes were measured by means of pyrogallo autoxidation. |
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| Keywords: | BENZIMIDAZOLE P PROPANAMINE P SUPEROXIDE DISMUTASE QUANTUM CHEMISTRY ZINC COMPLEX CRYSTAL STRUCTURE ELECTRONIC STRUCTURE BIOLOGICAL ACTIVITY |
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