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薄层液/液界面电子转移动力学的研究进展
引用本文:刘秀辉,张立敏,胡丽娜,卢小泉.薄层液/液界面电子转移动力学的研究进展[J].分析化学,2006,34(1):135-139.
作者姓名:刘秀辉  张立敏  胡丽娜  卢小泉
作者单位:西北师范大学化学化工学院,兰州,730070
基金项目:国家自然科学重点基金(No.20335030),教育部第四届高校青年教师科研奖励计划基金(No.TRAPOYT),甘肃省自然科学基金(No.3ZS051-A25-023)资助项目
摘    要:薄层循环伏安法是研究液/液界面电荷转移的一种新方法,具有简单、快速、易操作的优点。文章回顾了液/液界面电化学的发展历史,介绍了薄层法的实验原理,对其在电化学中的应用和研究进展进行了评述,总结了界面驱动力与电子转移速率的关系。

关 键 词:液/液界面  薄层循环伏安法  界面电子转移  评述
收稿时间:2005-04-18
修稿时间:2005-04-182005-07-10

Progress in the Study of Electron Transfer Across Liquid/liquid Interfaces Using Thin Layer Method
Liu Xiuhui, Zhang Limin, Hu Lina, Lu Xiaoquan.Progress in the Study of Electron Transfer Across Liquid/liquid Interfaces Using Thin Layer Method[J].Chinese Journal of Analytical Chemistry,2006,34(1):135-139.
Authors:Liu Xiuhui  Zhang Limin  Hu Lina  Lu Xiaoquan
Abstract:Thin-layer cyclic voltammetry(TLCV) is a novel method for studying the charge transfer at(liquid/liquid) interface recently.It has many advantages such as simplicity,rapidity and convenience.The(paper) gives a brief introduction of the electrochemistry of electron transfer across liquid/liquid interfaces and its experiment principle using thin layer method.The application and progress of the thin layer method in the study of electron transfer across liquid/liquid interface is reviewed.In addition,the relationship between the driving force and the rate of electron transfer across the interface is summarized.43 papers are cited.
Keywords:Liquid/liquid interface  thin-layer cyclic voltammetry  electron transfer  review
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