A first transition series pseudotetrahedral oxynitride anion: synthesis and characterization of Ba(2)VO(3)N |
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| Authors: | Clarke Simon J Chalker Paul R Holman Jasper Michie Charles W Puyet Matthieu Rosseinsky Matthew J |
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| Institution: | Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford OX1 3QR, U.K. simon.clarke@chem.ox.ac.uk |
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| Abstract: | Ammonolysis of reactive oxide precursors affords the vanadium(V) phase Ba(2)VO(3)N that is shown by X-ray and neutron powder diffraction and Raman spectroscopy to contain pseudotetrahedral VO(3)N(4-) anions. This is the first example of such species for the first transition series metals. |
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