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Le metaplombate et le triplombate de potassium
Affiliation:1. Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude 670047, Russia;2. Department of Chemistry, Buryat State University, Ulan-Ude 670000, Russia;3. Laboratory of Optical Materials and Structures, Rzhanov Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia;4. Functional Electronics Laboratory, Tomsk State University, Tomsk 634050, Russia;5. Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk 630090, Russia;6. Laboratory of Crystal Chemistry, Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk 630090, Russia;7. Department of Natural Sciences, Novosibirsk State University, Novosibirsk 630090, Russia;8. Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, SB RAS, Krasnoyarsk 660036, Russia;9. Laboratory of Epitaxial Layers, Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk 630090, Russia;10. Laboratory of Research Methods of Composition and Structure of Functional Materials, Novosibirsk State University, Novosibirsk 630090, Russia;11. Laboratory of Crystal Structure, Kirensky Institute of Physics, SB RAS, Krasnoyarsk 660036, Russia;12. Department of Photonics and Laser Technology, Siberian Federal University, Krasnoyarsk 660079, Russia;13. Laboratory of Condenced Matter Spectroscopy, Institute of Automation and Electrometry, SB RAS, Novosibirsk 90, 630090, Russia;1. School of Chemistry, The University of Sydney, Sydney, NSW, 2006, Australia;2. Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW, 2234, Australia;3. Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168, Australia;4. Institute of Energy and Climate Research (IEK-6), Forschungszentrum Jülich GmbH, 52428, Jülich, Germany;5. Institute für Kristallographie, RWTH Aachen University, 52066, Aachen, Germany;1. Chimie ParisTech, PSL Research University, CNRS, Institut de Recherche de Chimie Paris (IRCP), F-75005 Paris, France;2. European Commission, Joint Research Centre, P.O. Box 2340, 76125 Karlsruhe, Germany;3. Delft University of Technology, Faculty of Applied Sciences, Department of Radiation Science & Technology, Nuclear Energy and Radiation Applications (NERA), Mekelweg 15, 2629 JB, Delft, The Netherlands;4. Sorbonne University, UPMC Université, Paris 06, 75005 Paris, France;1. Asahi Glass Co., Ltd, Research Center, 1150Hazawa-cho, Kanagawa-ku, Yokohama 221-8755, Japan;2. Tokyo University of Science, Department of Materials Science and Technology, Japan;1. Helmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology, Bautzner Landstrasse 400, 01328, Dresden, Germany;2. Rossendorf Beamline (BM20-CRG), European Synchrotron Radiation Facility, 6 rue Jules Horowitz, BP 220, 38043, Grenoble, France;3. European Commission, Joint Research Centre (JRC), Postfach 2340, 76125, Karlsruhe, Germany;4. CEA, Nuclear Energy Division, Research Department on Mining and Fuel Recycling Processes, SFMA, BP 17171, F-30207, Bagnols-sur-Cèze, France
Abstract:Two new potassium plumbates are prepared by action of anhydrous KOH on its melting point on PbO2: the metaplumbate K2PbO3 and the triplumbate K2Pb3O7. They are isostructural with previously studied K2SnO3 and K2Sn3O7. Some properties of both compounds are given.
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