| 具有[344484]笼状结构单元的微孔磷酸镓Ga3P2O8(OH)3(H2O)的合成、晶体结构及表征 |
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| 引用本文： | 杜宇,于吉红,李激扬,潘勤鹤,徐如人. 具有[344484]笼状结构单元的微孔磷酸镓Ga3P2O8(OH)3(H2O)的合成、晶体结构及表征[J]. 无机化学学报, 2006, 22(8): 1503-1506 |
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| 作者姓名： | 杜宇 于吉红 李激扬 潘勤鹤 徐如人 |
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| 作者单位： | 吉林大学化学学院，无机合成与制备化学国家重点实验室，长春 130012,吉林大学化学学院，无机合成与制备化学国家重点实验室，长春 130012,吉林大学化学学院，无机合成与制备化学国家重点实验室，长春 130012,吉林大学化学学院，无机合成与制备化学国家重点实验室，长春 130012,吉林大学化学学院，无机合成与制备化学国家重点实验室，长春 130012 |
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| 基金项目： | 国家自然科学基金;国家重点基础研究发展计划(973计划) |
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| 摘 要： | Open-framework metal phosphates have been the subject of intense research owing to their interesting structural chemistry and potential applications in catalysis and ion exchange. The gallium phosphate family has exhibits rich structural chemistry. A novel gallium phosphate Ga3P2O8(OH)3(H2O)(GaPO-CJ36) has been prepared in a hydrothermal reaction system of GaO(OH)-H3PO4-Co(chxn)3Cl3-H2O at 180 ℃ for 7 days. Single-crystal X-ray analysis shows that GaPO-CJ36 crystallizes in the P21/c space group with a=1.833 35(12) nm, b=0.503 94(3) nm, c=1.062 90(9) nm, V=0.982 01(12) nm3, and Z=4. The connection of GaO2(OH)3(H2O) octahedra, PO4 and GaO4 tetrahedra through vertex oxygen atoms forms a three-dimensional open framework, which contains 8-ring channels along the [010] direction. Its structure is composed of interesting [344484] cages, which have not been found in known gallium phosphates. CSD: 416779.
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| 关 键 词： | 磷酸镓； 水热合成； 晶体结构 |
| 文章编号： | 1001-4861(2006)08-1503-04 |
| 收稿时间： | 2006-06-12 |
| 修稿时间： | 2006-07-27 |
Synthesis and Structure of a Novel Microporous Gallium Phosphate Ga3P2O8(OH)3(H2O) Containing [344484] Cages |
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| DU Yu,YU Ji-Hong,LI Ji-Yang,PAN Qin-He and XU Ru-Ren. Synthesis and Structure of a Novel Microporous Gallium Phosphate Ga3P2O8(OH)3(H2O) Containing [344484] Cages[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(8): 1503-1506 |
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| Authors: | DU Yu YU Ji-Hong LI Ji-Yang PAN Qin-He XU Ru-Ren |
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| Affiliation: | State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012,State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012,State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012,State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 |
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| Abstract: | |
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| Keywords: | gallium phosphate hydrothermal synthesis crystal structure |
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