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萘并吡喃类固态光致变色化合物的合成及性能研究
引用本文:寇希元,王永梅,徐黎立,孟继本,温珍珍.萘并吡喃类固态光致变色化合物的合成及性能研究[J].高等学校化学学报,2000,21(5):717-720.
作者姓名:寇希元  王永梅  徐黎立  孟继本  温珍珍
作者单位:1. 国家海洋局天津海水淡化研究所
2. 南开大学化学系,天津,300071
基金项目:南开大学吸附分离功能高分子材料国家重点实验室
摘    要:合成了化合物 2,2-二芳基萘并吡喃(2a-2p),产物结构和组成通过1H NMR, MS和元素分析证实.测定了化合物光照前后的紫外可见吸收光谱.部分化合物表现出良好的固态光致变色性能,分析了它们的结构与光致变色性能间的关系.

关 键 词:2  2-二芳基萘并吡喃  固态光致变色  合成  结构

Studies on the Synthesis and Properties of Solid State Photochromism from 2,2-Diarylnaphthopyrans
KOU Xi-Yuan,WANG Yong-Mei,XU Li-Li,MENG Ji-Ben,WEN Zhen-Zhen.Studies on the Synthesis and Properties of Solid State Photochromism from 2,2-Diarylnaphthopyrans[J].Chemical Research In Chinese Universities,2000,21(5):717-720.
Authors:KOU Xi-Yuan  WANG Yong-Mei  XU Li-Li  MENG Ji-Ben  WEN Zhen-Zhen
Abstract:The title compounds were first designed and synthesized, the structures of all the compounds have been confirmed by 1H NMR, MS and elemental analysis. Combined with UV-Vis, the photochromism of these compounds was studied intensively. It was found that some of the 2, 2- diarylnaphthopyran compounds showed a good photochromism in the solid state, changing color quickly. Moreover, the relationship between the structure and photochromism properties was analyzed.
Keywords:2  2-Diarylnaphthopyran  Solid state photochromism  Synthesis  Structure  
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