Formation of furan derivatives in the course of the Stevens rearrangement of ammonium salts containing 4-allyloxy(phenoxy)-2-butynyl group |
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| Authors: | M. O. Manukyan A. V. Babakhanyan G. A. Panosyan A. Kh. Gyul’nazaryan S. T. Kocharyan |
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| Affiliation: | (1) Institute of Organic Chemistry, National Academy of Sciences of Armenia, ul. Z. Kanakertsi 167A, Yerevan, 0091, Armenia;(2) Abovyan Armenian State Pedagogical University, Yerevan, Armenia;(3) Center for Studying Molecular Structures, National Academy of Sciences of Armenia, Yerevan, Armenia |
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| Abstract: | ![]()
Ammonium salts containing phenacyl group in combination with 4-allyloxy(phehoxy)-2-butynyl group, when treated with a suspension of potassium hydroxide in benzene, undergo the 3,2-Stevens rearrangement with the formation of allenic amino ketones which under the reaction conditions give the furan derivatives. |
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