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Chemo‐selective copper‐catalyzed C‐O coupling reactions of phenols with aryl/vinyl halides using enaminone as efficient ligand
Authors:Jie‐Ping Wan  Chunping Wang  Yunyun Liu
Institution:College of Chemistry and Chemical Engineering, Jiangxi Normal University, , Nanchang, 330022 China
Abstract:The copper‐catalyzed Ullmann C‐O coupling reactions between phenols and aryl/vinyl halides have been efficiently performed by employing (E)‐3‐(dimethylamino)‐1‐(2‐hydroxyphenyl)prop‐2‐en‐1‐one, an easily available enaminone, as ligand. This new ligand is advantageous for its easy availability, broad applicability and good efficiency. Copyright © 2012 John Wiley & Sons, Ltd.
Keywords:copper catalysis  C‐O  coupling  enaminone  ligand  aryl ethers  vinyl ethers
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