Dinuclear Pd(II)–NHC complex derived from proline and its application toward Mizoroki–Heck reaction performed in water |
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| Authors: | Ming‐Tao Ma Jian‐Mei Lu |
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| Institution: | College of Chemistry and Materials Engineering, Wenzhou University, , Wenzhou, Zhejiang Province, 325035 People's Republic of China |
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| Abstract: | A novel dinuclear Pd(II)–N‐heterocyclic carbene complex derived from proline was successfully synthesized and its structure was confirmed unambiguously by X‐ray single‐crystal diffraction. Furthermore, the complex was found to be a good catalyst in the Mizoroki–Heck reaction of aryl iodides and bromides with acrylic acid performed in pure water. Copyright © 2012 John Wiley & Sons, Ltd. |
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| Keywords: | N‐heterocyclic carbene proline dinuclear palladium complex Mizoroki– Heck reaction water |
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