Coordination compounds of 1,4-dihydroxybenzoquinone and its homologues. Structures and properties |
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| Institution: | 1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan;2. Department of Chemistry, Faculty of Science, Shizuoka University, Oya, Shizuoka 422-8529, Japan;1. Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal;2. Department of Chemistry, Baku State University, Z. Xalilov Str. 23, Az 1148 Baku, Azerbaijan;1. Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, 999078 Macau SAR, China;2. Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, Avenida da Universidade, Taipa, 999078 Macau SAR, China;3. Henan Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University, 436 Xian’ge Road, Anyang 455000, China;4. National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China;5. Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials, Suzhou Institute of Nano-Tech and Nano-Bionics, Nanchang, Chinese Academy of Sciences, Nanchang, 330200, China;1. Department of Civil & Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 133-791, Republic of Korea;2. Central Scientific Instruments Organisation (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India;3. Analytical Science Division, National Physical Laboratory, Teddington TW11 0LW, UK;1. Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan;2. Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan;3. Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Kyoto 615-8520, Japan |
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| Abstract: | Metal complexes of 1,4-dihydroxy-benzoquinone and its homologues (H2C6X2O4) are reviewed, focusing on assembled structures based on their X-ray crystallographic structures reported so far. A wide variety of crystal structures based on mononuclear, binuclear, polynuclear complexes and extended structures of coordination polymers or hydrogen bond linked networks are listed in relation to the coordination modes such as the monodentate, bidentate, and bis-bidentate form of the ligands. Their physico-chemical properties such as redox, UV–vis, EPR and magnetic properties are described. The ligand, H2C6X2O4, discussed here is one of the most useful multifunctional ligands, affording not only various self-assembled frameworks via coordination, hydrogen, and coulomb linkages, but also unique electronic structures, which are accompanied by charged and spin states. Their characteristics are mentioned in detail. |
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