School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
Abstract:
A novel polyethylene glycol(PEG)-200-based dicationic acidic ionic liquid(PEG200-DAIL)was used to synthesize HMX from DPT by nitrolysis with N2O5.It was found that either N2O5 or PEG200-DAIL could improve the yield.Furthermore,the combined use of PEG200-DAIL and N2O5 could increase the yield of HMX to 64%with the used quantity of HNO3 decreased.dramatically