Synthesis, photophysics, electrochemistry, theoretical, and transient absorption studies of luminescent copper(I) and silver(I) diynyl complexes. X-ray crystal structures of [Cu3(micro-dppm)3(micro3-eta1-C triple bond CC triple bond CPh)2]PF6 and [Cu3(micro-dppm)3(micro3-eta1-C triple bond CC triple bond CH)2]PF6 |
| |
| Authors: | Lo Wing-Yin Lam Chi-Ho Yam Vivian Wing-Wah Zhu Nianyong Cheung Kung-Kai Fathallah Sofiane Messaoudi Sabri Le Guennic Boris Kahlal Samia Halet Jean-François |
| |
| Institution: | Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and HKU-CAS Joint Laboratory of New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, People's Republic of China. |
| |
| Abstract: | A series of soluble trinuclear copper(I) and silver(I) complexes containing bicapped diynyl ligands, M(3)(micro-dppm)(3)(micro(3)-eta(1)-C triple bond CC triple bond CR)(2)]PF(6) (M = Cu, R = Ph, C(6)H(4)-CH(3)-p, C(6)H(4)-OCH(3)-p, (n)C(6)H(13), H; M = Ag, R = Ph, C(6)H(4)-OCH(3)-p), has been synthesized and their electronic, photophysical, and electrochemical properties studied. The X-ray crystal structures of Cu(3)(micro-dppm)(3)(micro(3)-eta(1)-C triple bond CC triple bond CPh)(2)]PF(6) and Cu(3)(micro-dppm)(3)(micro(3)-eta(1)-C triple bond CC triple bond CH)(2)]PF(6) have been determined. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
